 |
9-Fluorenemethanol
- Iupac Name:9H-fluoren-9-ylmethanol
- CAS No.: 24324-17-2
- Molecular Weight:196.249
- Modify Date.: 2022-11-25 02:25
- Introduction:
9-Fluorenemethanol, with the chemical formula C14H12O and CAS registry number 24324-17-2, is a compound known for its applications in various chemical processes. This white solid, also referred to as fluorenylmethanol, is characterized by its fluorene and hydroxyl functional groups. It is commonly used as a building block in organic synthesis, offering a versatile platform for the introduction of fluorene moiety into different molecules. 9-Fluorenemethanol has been studied for its potential use in the development of organic light-emitting diodes (OLEDs) and as a precursor for the synthesis of various pharmaceutical compounds. It exhibits good thermal stability and can be easily functionalized to introduce desired properties. Further research is being conducted to explore its potential applications in the field of materials science and drug discovery.
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1. Names and Identifiers
- 1.1 Name
- 9-Fluorenemethanol
- 1.2 Synonyms
(9H-Fluoren-9-yl)methanol(9H-Fluoren-9-yl)-methanol(ethylthio)formic acid (5-nitro-1-indazolyl)methyl ester9-(Hydroxymethyl)fluorene,9-Fluorenylmethanol9-Fluorenyl Methanol9-FLUORENYLMENTHANOL9-fluorenylmethanol9H-Fluoren-9-ylmethanol9H-Fluorene-9-methanol9-HydroxymethylfluoreneAKOS MSC-0133EINECS 246-167-5fluoren-9-ylmethan-1-olFluorene-9-methanolFluorenemethanolfluorenyl methanolFmoc (9-Fluorenemethanol)Fmoc-Oh(9-Fluorenylmethanol)MFCD00001139TIMTEC-BB SBB008508
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- 1.3 CAS No.
- 24324-17-2
- 1.4 CID
- 90466
- 1.5 EINECS(EC#)
- 246-167-5
- 1.6 Molecular Formula
- C14H12O (isomer)
- 1.7 Inchi
- InChI=1S/C14H12O/c15-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14-15H,9H2
- 1.8 InChIkey
- XXSCONYSQQLHTH-UHFFFAOYSA-N
- 1.9 Canonical Smiles
- C1=CC=C2C(=C1)C(C3=CC=CC=C32)CO
- 1.10 Isomers Smiles
- C1=CC=C2C(=C1)C(C3=CC=CC=C32)CO
2. Properties
- 2.1 Density
- 1.175
- 2.1 Melting point
- 104-107℃
- 2.1 Boiling point
- 337
- 2.1 Refractive index
- 1.638
- 2.1 Flash Point
- 167.4°C
- 2.1 Precise Quality
- 196.08900
- 2.1 PSA
- 20.23000
- 2.1 logP
- 2.79120
- 2.1 Solubility
- Soluble in methanol.
- 2.2 Appearance
- White to pale yellow Crystalline Powder
- 2.3 Storage
- Ambient temperatures.
- 2.4 Chemical Properties
- WHITE TO PALE YELLOW CRYSTALLINE POWDER 9-Fluorenemethanol Preparation Products And Raw materials Preparation Products
- 2.5 Color/Form
- Solid
- 2.6 pKa
- 13.68±0.10(Predicted)
- 2.7 Water Solubility
- soluble in methanol.
- 2.8 Stability
- Stable under normal temperatures and pressures.
- 2.9 StorageTemp
- Sealed in dry,Room Temperature
3. Safety and Handling
- 3.1 Hazard Codes
- Xi
- 3.1 Risk Statements
- R36/37/38
- 3.1 Safety Statements
- S24/25
- 3.1 Packing Group
- I; II; III
- 3.1 RIDADR
- NONH for all modes of transport
- 3.1 WGK Germany
- 3
4. MSDS
2.Hazard identification
2.1 Classification of the substance or mixture
no data available
2.2 GHS label elements, including precautionary statements
Pictogram(s) | no data available |
Signal word | no data available |
Hazard statement(s) | no data available |
Precautionary statement(s) | |
Prevention | no data available |
Response | no data available |
Storage | no data available |
Disposal | no data available |
2.3 Other hazards which do not result in classification
no data available
6. Synthesis Route
24324-17-2Total: 27 Synthesis Route
8. Other Information
- 8.0 Usage
- 9-Fluorenylmethanol acts as a N-protecting reagent, which is used in the synthesis of peptide. It is also used in the preparation of deoxynucleoside 9-fluorenemethyl phosphorodithioates. Further, it is used to prepare 9-(fluoromethyl)fluorene. In addition to this, it is involved in the electropolymerization with boron trifluoride diethyl etherate to yield low-potential electrodeposition of semiconducting poly(9-fluorenemethanol) film.
- 8.1 BRN
- 2330017
- 8.2 Chemical Properties
- WHITE TO PALE YELLOW CRYSTALLINE POWDER
- 8.3 Uses
-
9-Fluorenemethanol, N-protecting reagent, was used in the peptide syntheses. 9-Fluorenemethanol was also used in the synthesis of deoxynucleoside 9-fluorenemethyl phosphorodithioates.
- 8.4 Mesh Entry Terms
- 9-fluorenylmethanol
- 8.5 Manufacturing Info
- 9H-Fluorene-9-methanol: INACTIVE
9. Computational chemical data
- Molecular Weight: 196.249g/mol
- Molecular Formula: C14H12O
- Compound Is Canonicalized: True
- XLogP3-AA: 2.7
- Exact Mass: 196.088815002
- Monoisotopic Mass: 196.088815002
- Complexity: 203
- Rotatable Bond Count: 1
- Hydrogen Bond Donor Count: 1
- Hydrogen Bond Acceptor Count: 1
- Topological Polar Surface Area: 20.2
- Heavy Atom Count: 15
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count: 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Isotope Atom Count: 0
- Covalently-Bonded Unit Count: 1
- CACTVS Substructure Key Fingerprint: AAADccBwIAAAAAAAAAAAAAAAAAAAAYAAAAAwYAAAAAAAAGABQAAAGgAACAAADQCgmAIwAIAAAgCAAiBCAAACAAAgAAAIiAAAAIgIMCKAERCAYAAkwAEIiAeAwPAOgAAAAAAQAAAAAAAAACAAAQAACAAAAA==
10. Question & Answer
-
Overview 9-Fluorenemethanol is a commonly used protecting reagent in organic synthesis, with a molecular formula of C14H12O and a molecular weight of 196.25. It is a white or pale yellow crystalline p..
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Introduction 9-Fluorenemethanol is a highly important chemical intermediate that finds increasing applications in pharmaceuticals, functional dyes, and polymers. In recent years, it has become a cruci..
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