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Rosin structure
Rosin structure

Rosin

Iupac Name:1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid
CAS No.: 8050-09-7
Molecular Weight:302.5
Modify Date.: 2022-11-05 21:57
Introduction:
Rosin, also known as colophony, is a natural resin derived from pine trees. It is obtained by distilling the sap or gum of various species of pine trees. Rosin has a chemical formula of C20H30O2 and a CAS registry number of 8050-09-7. This compound is commonly used in a variety of industries, including adhesives, coatings, and soldering fluxes. It is known for its sticky and adhesive properties, making it ideal for applications that require strong bonding. Rosin is also used in the production of violin bows, as it provides friction and grip on the strings. Additionally, it is used in the manufacturing of printing inks, varnishes, and sealing wax. Overall, rosin is a versatile compound with a wide range of applications in various industries.
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1. Names and Identifiers
1.1 Name
Rosin
1.2 Synonyms

(5Β,9Β)-Abieta-7,13-dien-19-oic acid 1-Phenanthrenecarboxylic acid, 1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-, (1S,4aR,4bS,10aS)- EINECS 232-475-7 Gum rosin MFCD00132205

1.3 CAS No.
8050-09-7
1.4 CID
10569
1.5 EINECS(EC#)
232-475-7
1.6 Molecular Formula
C20H30O2 (isomer)
1.7 Inchi
InChI=1S/C20H30O2/c1-13(2)14-6-8-16-15(12-14)7-9-17-19(16,3)10-5-11-20(17,4)18(21)22/h7,12-13,16-17H,5-6,8-11H2,1-4H3,(H,21,22)/t16-,17+,19+,20+/m0/s1
1.8 InChIkey
RSWGJHLUYNHPMX-ONCXSQPRSA-N
1.9 Canonical Smiles
CC(C)C1=CC2=CCC3C(C2CC1)(CCCC3(C)C(=O)O)C
1.10 Isomers Smiles
CC(C)C1=CC2=CC[C@@H]3[C@@]([C@H]2CC1)(CCC[C@@]3(C)C(=O)O)C
2. Properties
2.1 Density
1,07 g/cm3
2.1 Melting point
70-72°C
2.1 Boiling point
439.5°Cat760mmHg
2.1 Refractive index
1.5400
2.1 Flash Point
180°C
2.1 Precise Quality
302.224579
2.1 PSA
37.30000
2.1 logP
5.20620
2.1 Solubility
chloroform: 0.1?g/mL, clear, strongly yellow
2.2 Appearance
light yellow
2.3 Chemical Properties
solid with a slight odour of turpentine
2.4 Color/Form
Crystals from alcohol, petroleum ether
2.5 Water Solubility
chloroform: 0.1?g/mL, clear, strongly yellow | Soluble in alcohol, benzene, ether. Insoluble in water
2.6 Spectral Properties
MASS: 72194 (NIST/EPA/MSDC Mass Spectral Database, 1990 version)
IR: 130 (Sadtler Research Laboratories IR grating collection)
UV: 173 (Sadtler Research Laboratories spectral collection)
1H NMR: 707 (Sadtler Research Laboratories spectral collection)
2.7 Stability
Stable. Combustible. Incompatible with oxidizing agents.
3. Use and Manufacturing
3.1 Usage
Colophony is a yellow resin in the production of varnishes, printing inks, paper, soldering fluxes, greases, cutting fluids, glue tackifiers,adhesives, surface coatings, polish, insulations, waxes, cosmetics (mascara, rouge, eye shadow), topical medicaments, shoes, violin bowrosin, day, athletic grip aid, pine-oil cleansers; component in dental impression materials and periodontal packings.
4. Safety and Handling
4.1 Symbol
GHS07
4.1 Hazard Codes
Xi
4.1 Signal Word
Warning
4.1 Risk Statements
43
4.1 Safety Statements
24-37
4.1 Octanol/Water Partition Coefficient
log Kow = 6.06
4.2 Other Preventative Measures
SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.
In case of skin contact: Wash off with soap and plenty of water. Consult a physician.
In case of eye contact: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Handling: Avoid formation of dust and aerosols.
Hygiene measures: Handle in accordance with good industrial and safety practice. Wash hands before breaks and at the end of workday.
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4.3 Hazard Declaration
H317
4.3 Cleanup Methods
Personal precautions: Use personal protective equipment. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation.
Environmental precautions: Do not let product enter drains.
Methods for cleaning up: Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal.
4.4 DisposalMethods
SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational exposure or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in soil or water; effects on animal, aquatic, and plant life; and conformance with environmental and public health regulations.
Observe all federal, state, and local environmental regulations.
4.5 RIDADR
225kgs
4.5 Fire Fighting Procedures
Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special protective equipment for fire-fighters: Wear self contained breathing apparatus for fire fighting if necessary.
4.6 Caution Statement
P280
4.6 WGK Germany
1
4.6 RTECS
VL0480000
4.6 Protective Equipment and Clothing
Personal protective equipment: Respiratory protection- Where risk assessment shows air-purifying respirators are appropriate use a dust mask type N95 (US) or type P1 (EN 143) respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hand protection- Handle with gloves. For prolonged or repeated contact use protective gloves. Eye protection- Safety glasses.
Hand protection: Handle with gloves. For prolonged or repeated contact use protective gloves.
Eye protection: Safety glasses.
Skin and body protection: Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Provide appropriate exhaust ventilation at places where dust is formed. Normal measures fro preventive fire protection.
4.7 Reactivities and Incompatibilities
Materials to avoid: Bases, acid chlorides, acid anhydrides, oxidizing agents, brass, copper.
4.8 Skin, Eye, and Respiratory Irritations
May cause respiratory tract irritation. May be harmful if absorbed through skin. May cause skin irritation. May cause eye irritation.
4.9 Safety
A poison by ingestion and inhalation route. When heated to decomposition it emits acrid smoke and irritating vapors.
5. MSDS

2.Hazard identification

2.1 Classification of the substance or mixture

Skin sensitization, Category 1

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Warning

Hazard statement(s)

H317 May cause an allergic skin reaction

Precautionary statement(s)
Prevention

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P272 Contaminated work clothing should not be allowed out of the workplace.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

Response

P302+P352 IF ON SKIN: Wash with plenty of water/...

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P321 Specific treatment (see ... on this label).

P362+P364 Take off contaminated clothing and wash it before reuse.

Storage

none

Disposal

P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

6. Other Information
6.0 Usage
Rosin is an ingredient in?printing?inks, photocopying and laser printing paper,?varnishes,?adhesives?(glues),?soap,?paper?sizing,?soda, soldering?fluxes and?sealing wax. It can be used as a glazing agent in medicines and chewing gum. In industry, rosin is a flux used in soldering. A mixture of pitch and rosin is used to make a surface against which glass is polished when making optical components such as lenses.
7. Computational chemical data
  • Molecular Weight: 302.5g/mol
  • Molecular Formula: C20H30O2
  • Compound Is Canonicalized: True
  • XLogP3-AA: 4.8
  • Exact Mass: 302.224580195
  • Monoisotopic Mass: 302.224580195
  • Complexity: 542
  • Rotatable Bond Count: 2
  • Hydrogen Bond Donor Count: 1
  • Hydrogen Bond Acceptor Count: 2
  • Topological Polar Surface Area: 37.3
  • Heavy Atom Count: 22
  • Defined Atom Stereocenter Count: 4
  • Undefined Atom Stereocenter Count: 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Isotope Atom Count: 0
  • Covalently-Bonded Unit Count: 1
  • CACTVS Substructure Key Fingerprint: AAADceB4MAAAAAAAAAAAAAAAAAAAAAAAAAAwQIAAAAAAAACAAAAAGgAACAAADwCAgAACCAAAAgCIAiDSCAAAAAAgAAAACAEAAAgIABIAAQAAQAAEgAAIgAOIyPCPgAAAAAAAAAAAAAQAACAAAAAAAAAAAA==
8. Question & Answer
  • Introduction: Rosin itself is not generally toxic, but in some cases, it may cause allergic reactions or respiratory tract stimuli. When people use or contact Rosin, they should pay attention to prop..
  • Introduction: Rosin is a natural resin, which is generally composed of substances secreted by pine trees and other pine species. It is widely used in the production of various industries and arts, in..
  • Rosin is a solid resin obtained from pine trees used for various applications, including as soap. Rosin contains numerous lipid-soluble acids and has previously demonstrated antibacterial activity aga..
  • If you eat enough of it, there will be an impact on your body of some kind. Touching it will only have the toxic impact if you are allergic.
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10. Realated Product Infomation