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Home> Encyclopedia >Inorganic Salts>Other Chemicals>Organic Intermediate
Barium chromate structure
Barium chromate structure

Barium chromate

Iupac Name:barium(2+);dioxido(dioxo)chromium
CAS No.: 10294-40-3
Molecular Weight:253.3207
Modify Date.: 2022-11-09 02:40
Introduction: Barium chromate isa pigment almost entirely in anticorrosion jointing pastes to prevent electro-chemical corrosion at junctions of dissimilar metals; some use in artists' colors and in coloring glass, ceramics, porcelain. Also used in metal primers, pyrotechnic compositions. View more+
1. Names and Identifiers
1.1 Name
Barium chromate
1.2 Synonyms

Barium chromate (1:1) Barium chromate (BaCrO4) Barium chromate(VI) Barium Chromate, Puratronic (Metals Basis) Barium chromate: chromic acid, barium salt Barium chromium oxide (BaCrO4) Barium cromate Barium yellow Baryta yellow C.I. 77103 C.I. Pigment Yellow 31 c.i.77103 c.i.pigmentyellow31 Chromic acid (H2CrO4), barium salt (1:1) Chromic acid (H2-CrO4), barium salt (1:1) Chromic acid, barium salt (1:1) Lemon chrome Lemon Yellow Lemon Yellow (inorganic pigment) OP 206 Permanent yellow Pigment Yellow 31 Ultramarine yellow

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1.3 CAS No.
10294-40-3
1.4 CID
25136
1.5 EINECS(EC#)
233-660-5
1.6 Molecular Formula
BaCrO4 (isomer)
1.7 Inchi
InChI=1S/Ba.Cr.4O/q+2;;;;2*-1
1.8 InChIkey
QFFVPLLCYGOFPU-UHFFFAOYSA-N
1.9 Canonical Smiles
[O-][Cr](=O)(=O)[O-].[Ba+2]
1.10 Isomers Smiles
[O-][Cr](=O)(=O)[O-].[Ba+2]
2. Properties
2.1 Density
4.5
2.1 Melting point
210℃ (dec.)
2.1 Boiling point
°Cat760mmHg
2.1 Flash Point
°C
2.1 Precise Quality
253.82500
2.1 PSA
80.26000
2.1 logP
-0.47520
2.1 Appearance
yellow powder
2.2 Storage
Ambient temperatures.
2.3 Chemical Properties
heavy, yellow powder(s); rhomb, monoclinic; prepared from BaCl2 and Na2CrO4solutions, followed by filtering resulting precipitate; used in safety matches, as a corrosion inhibitor [MER06] [HAW93]
2.4 Physical Properties
Yellow orthorhombic crystal; density 4.50 g/cm3; darkens on heating; insoluble in water and organic solvents; dissolves in mineral acid with decomposition.
2.5 Color/Form
Yellow heavy monoclinic orthorhombic crystals
Greenish-yellow crystals
2.6 Decomposition
Dissolved or decomposed by mineral acids
2.7 Odor
Odorless
2.8 PH
... hexavalent chromium compounds are acidic
2.9 Water Solubility
insoluble
2.10 Stability
Stable. Oxidizer. May react vigorously with reducing agents.
3. Use and Manufacturing
3.1 Usage
Barium chromate isa pigment almost entirely in anticorrosion jointing pastes to prevent electro-chemical corrosion at junctions of dissimilar metals; some use in artists' colors and in coloring glass, ceramics, porcelain. Also used in metal primers, pyrotechnic compositions.
4. Safety and Handling
4.1 Hazard Codes
T
4.1 Risk Statements
R49;R8;R20/22;R43;R50/53
4.1 Safety Statements
S53;S36/37;S45;S60;S61
4.1 Packing Group
III
4.1 Hazard Class
5.1
4.1 DisposalMethods
SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.
4.2 RIDADR
UN 1479
4.2 Safety Profile
Confirmed humancarcinogen. A poison. Mutation datareported. Reacts vigorously with reducingmaterials. See also BARIUMCOMPOUNDS (soluble) andCHROMIUM COMPOUNDS. Used inpyrotechnics and as an explosive initiator. Barium chromate Preparation Products And Raw materials Raw materials
4.3 Formulations/Preparations
Grades: technical; chemically pure.
98.5% min
-80 mesh, 99.5% purity grade; 99% grade
4.4 WGK Germany
3
4.4 RTECS
CQ8760000
4.4 Reactivities and Incompatibilities
Reacts vigorously with reducing materials.
Hydrazine is decomposed explosively by chromates. /Chromates/
4.5 Toxicity
sce-ham:ovr 100 mg/L MUREAV 156,219,85
5. MSDS

2.Hazard identification

2.1 Classification of the substance or mixture

Acute toxicity - Oral, Category 4

Acute toxicity - Inhalation, Category 4

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Warning

Hazard statement(s)

H302 Harmful if swallowed

H332 Harmful if inhaled

Precautionary statement(s)
Prevention

P264 Wash ... thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

Response

P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/\u2026if you feel unwell.

P330 Rinse mouth.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P312 Call a POISON CENTER/doctor/\u2026if you feel unwell.

Storage

none

Disposal

P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

6. Other Information
6.0 Merck
14,972
6.1 Chemical Properties
heavy, yellow powder(s); rhomb, monoclinic; prepared from BaCl2 and Na2CrO4solutions, followed by filtering resulting precipitate; used in safety matches, as a corrosion inhibitor [MER06] [HAW93]
6.2 Uses
As a pigment almost entirely in anticorrosion jointing pastes to prevent electro-chemical corrosion at junctions of dissimilar metals; some use in artists' colors and in coloring glass, ceramics, porcelain. Also used in metal primers, pyrotechnic compositions.
6.3 Hazard
Confirmed carcinogen.
6.4 Safety Profile
Confirmed human carcinogen. A poison. Mutation data reported. Reacts vigorously with reducing materials. See also BARIUM COMPOUNDS (soluble) and CHROMIUM COMPOUNDS. Used in pyrotechnics and as an explosive initiator.
6.5 Usage
Barium chromate is used as a pigment, oxidizing agent, colorant in glass, and sulfate scavenger in chromium electroplating baths, ceramics, and porcelain. It acts as a corrosion inhibitor in jointing pastes and metal primers. Further, it is used in fuses, safety matches, ignition control devices and high-temperature batteries. In addition to this, it is used as a carrier for the chromium ions and useful as a burn rate modifier in pyrotechnic compositions. It is involved as a catalyst in the alkane dehydration reaction.
6.6 Usage
Barium chromate has been found to be useful in many capacities. often the compound is used as a carrier for the chromium ions. is an oxidizing agent, making it useful as a burn rate modifier in pyrotechnic compositions. It is especially useful in delay compositions such as delay fuses. It is also used in the composition of a catalyst for alkane dehydration.
7. Computational chemical data
  • Molecular Weight: 253.3207g/mol
  • Molecular Formula: BaCrO4
  • Compound Is Canonicalized: True
  • XLogP3-AA: null
  • Exact Mass: 253.825410
  • Monoisotopic Mass: 253.825410
  • Complexity: 62.2
  • Rotatable Bond Count: 0
  • Hydrogen Bond Donor Count: 0
  • Hydrogen Bond Acceptor Count: 4
  • Topological Polar Surface Area: 80.3
  • Heavy Atom Count: 6
  • Defined Atom Stereocenter Count: 0
  • Undefined Atom Stereocenter Count: 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Isotope Atom Count: 0
  • Covalently-Bonded Unit Count: 2
  • CACTVS Substructure Key Fingerprint: AAADcQAAOAAAAACAAAAEAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA==
8. Question & Answer
  • In this article, we will delve into the methods and techniques for synthesizing and preparing Barium chromate, shedding light on the essential processes for obtaining this valuable chemical compound.I..
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